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Glycerin — A Versatile Polyol Humectant in Skincare

A naturally occurring polyol that helps improve stratum corneum hydration and skin feel. According to 2014 FDA VCRP data, glycerin was the third most frequently reported cosmetic ingredient, appearing in 15,654 product formulations. Its hydration performance depends on concentration, formulation, and environmental humidity — often paired with occlusive ingredients for best results.

Data sources: EU CosIng (#34040), CIR Safety Assessment (Final Report, December 2014), and SkinSenseDiary internal evaluation. Last updated: April 2026.

At a Glance

Also Known As
Glycerol, Glycerine, 甘油
CAS Number
56-81-5
CosIng Functions
Humectant, Skin Conditioning, Viscosity Controlling
Source
Natural (plant oils) / Synthetic
Korean Name
글리세린
Regulation
No restrictions

What Is Glycerin?

A powerful moisture-binding agent that attracts and retains water from the surrounding environment to help keep the skin surface hydrated and plump. It also helps improve product texture and feel while providing gentle skin conditioning benefits. This ingredient has an excellent safety profile and is generally well-tolerated, though individual tolerance may vary.


Glycerin (CAS No. 56-81-5) is a simple polyol compound with three hydroxyl groups and a molecular formula of C3H8O3. It is naturally occurring in all animals and plant matter as glycerides in fats and oils. For cosmetic use, natural glycerin is obtained as a byproduct in the conversion of fats and oils to fatty acids or fatty acid methyl esters (e.g., soap-making or biodiesel production). Synthetic glycerin can also be produced from propylene. It is completely miscible with water and has solvent properties similar to water and simple aliphatic alcohols, making it an incredibly versatile formulation ingredient.


According to 2014 FDA VCRP data, Glycerin is the third most frequently reported ingredient in the cosmetic database — after water and fragrance — appearing in 15,654 cosmetic products. Observed industry concentrations reach up to 79.2% in leave-on products and 99.4% in rinse-off products (CIR, 2014); these are maximum reported values, not recommended or regulatory limits. The FDA considers Glycerin GRAS (Generally Recognized As Safe) for food use, and it is also approved as an OTC drug for ear wax removal, skin protection, and oral care.

What Does Glycerin Do for Your Skin?

💧

Deep Hydration

As a humectant, glycerin attracts and binds water from the surrounding environment to the skin surface. Its three hydroxyl groups form hydrogen bonds with water molecules, providing lasting hydration without a heavy feel.

Smoother Skin Texture

By maintaining optimal moisture levels, glycerin reduces roughness and flakiness. It improves the appearance of fine lines caused by dehydration, giving skin a visibly smoother, more even texture.

🛡️

Barrier Protection

Glycerin strengthens the skin's natural moisture barrier, reducing trans-epidermal water loss (TEWL). A well-hydrated barrier is more resilient against environmental stressors and irritants.

🌿

Gentle & Versatile

Generally well-tolerated by most skin types, though individual sensitivity may vary. The CIR report confirmed no irritation at 50% concentration in subjects with dermatitis (n=420). Also acts as a viscosity modifier, improving product feel and spreadability.

Generally suitable for: Most skin types — dry, oily, combination, sensitive, and acne-prone. Individual tolerance may vary.

Is Glycerin Safe?

1 / 10

Low Hazard

The CIR Expert Panel (December 2014) concluded that glycerin is safe as a cosmetic ingredient in the practices of use and concentration described in their safety assessment. EU approved with no restrictions. FDA GRAS for food use.

Our rating is based on
CIR — Cosmetic Ingredient Review
Safe as Used (2014)
Expert Panel reviewed glycerin across 15,654 cosmetic formulations. Maximum observed industry concentrations: 79.2% (leave-on) and 99.4% (rinse-off) — these are reported values, not regulatory limits. Overall non-irritating (tested at 50%, n=420) and non-sensitizing (tested at 65.9%, n=48), though isolated individual reactions cannot be entirely excluded.
EU Cosmetics Regulation
No Restrictions
Not listed in Annex II (prohibited), III (restricted), or IV (colorants). Registered in CosIng as #34040. EU-wide unrestricted use in cosmetics.
Allergen & Sensitivity
No Known Allergens
Overall non-irritating at 50% in 420 subjects with dermatitis; isolated individual reactions cannot be entirely excluded. Non-sensitizing (65.9% in modified Draize, n=48; 100% patch test in factory workers, n=15). No GHS hazard codes.
Approved Functions
Humectant · Skin Conditioning · Viscosity Controlling
EU CosIng approved functions. Also listed as denaturant, hair conditioning, masking, oral care, perfuming, and skin protecting.

Things to Know

In very low-humidity environments, glycerin (like all humectants) used alone may feel less effective at maintaining skin hydration. Pair with an occlusive moisturizer (ceramides, squalane, or petrolatum) to lock in hydration.

At very high concentrations (above 30%), glycerin can feel sticky on the skin. Most effective consumer products use 2%–10% for optimal feel and efficacy.

The CIR Panel noted that glycerin derived from the Jatropha plant may contain phorbol esters. The FDA advises that glycerin from this source should not be used in cosmetics. Conventional impurity tests may not detect these toxins.

Pregnancy & Nursing

The CIR 2014 report reviewed multiple reproductive and developmental toxicity studies in animals. Oral NOAEL for maternal toxicity and teratogenicity: 1,310 mg/kg/d in rats, 1,280 mg/kg/d in mice, and 1,180 mg/kg/d in rabbits — with no fetal abnormalities observed in any species. No adverse effects were seen in rats administered 20% glycerin in drinking water throughout gestation and nursing; the F1 generation reproduced normally. Note: these findings are based on animal studies; no large-scale human clinical trials on topical glycerin during pregnancy have been published. Topical glycerin is generally considered safe during pregnancy, but always consult your healthcare provider.

Sources & References
Look up this ingredient on each authoritative source:
🔗 EWG Skin Deep🔗 PubMed🔗 EU CosIng🔗 ECHA🔗 FDA🔗 AAD🔗 CIR
Safety data compiled from CIR Safety Assessment of Glycerin (Final Report, December 2014), EU CosIng Database, and SkinSenseDiary internal analysis. This is for educational purposes only and does not constitute medical advice. Last updated: April 2026.

Pairing Guide for Glycerin

✓ Great Pairings

Hyaluronic Acid

Double humectant power: HA is known for its exceptional water-binding capacity while glycerin provides steady, long-lasting moisture. Complementary humectants that work well together.

Niacinamide (Vitamin B3)

Niacinamide strengthens the skin barrier while glycerin supplies hydration. Complementary mechanisms with no conflict.

Ceramides & Squalane

Occlusive ingredients that seal in the moisture glycerin attracts. The ideal partner to prevent water loss, especially in dry climates.

Retinol

Glycerin counteracts the dryness and peeling retinol can cause. Apply retinol first, then follow with glycerin-based moisturizer as a buffer layer.

⚠ Use with Care

Glycerin Alone in Dry Climates

Without an occlusive seal, glycerin used alone may feel less effective at maintaining hydration when humidity is below 40%. Always follow with a cream.

Very High Concentrations

Pure glycerin (above 30%) can feel sticky and may not absorb well. Dilute or choose products formulated at 2%–15% for best feel and efficacy.

Popular Products with Glycerin

Found in 34,603 product variants in our database. Here are some well-known options:

CeraVe
Foaming Cleanser with Niacinamide
Cleanser
Cetaphil
Hydrating Foaming Cream Cleanser
Cleanser
Bioderma
Hydrabio Gel-Cream Moisturiser
Moisturizer
Caudalie
VinoHydra Deep Hydration Moisturiser
Moisturizer
COSRX
The Peptide Collagen Hydrogel Eye Patch
Face Mask
The Ordinary
Squalane Cleanser
Cleanser

Frequently Asked Questions

Is Glycerin safe for sensitive skin?
Glycerin has a SkinSenseDiary safety rating of 1/10 (Low Hazard). The CIR Expert Panel (2014) concluded glycerin is safe as used in cosmetics. In a patch test with 420 subjects with dermatitis, glycerin at 50% was overall non-irritating, though isolated individual reactions cannot be entirely excluded. A modified Draize test with a 65.9% glycerin moisturizer (n=48) found no sensitization. It has no known allergen flags or GHS hazard codes in our database. Generally well-tolerated, though individual sensitivity may vary.
Can I use Glycerin every day?
Yes. Glycerin is generally gentle enough for twice-daily use. It is naturally occurring in all animal and plant tissues, including human skin and blood. The CIR report found no irritation at 50% under occlusion in subjects with dermatitis, and no adverse effects when 100% glycerin was applied to 30% of rabbit body surface 5 days/week for 45 weeks. It is one of the most widely used cosmetic ingredients, though individual tolerance may vary.
Can I use Glycerin with Retinol?
Yes, Glycerin and Retinol are a commonly recommended pairing. Glycerin provides hydration that may help counteract the dryness and irritation retinol can cause. Apply retinol first, then layer a glycerin-based moisturizer on top to buffer and hydrate the skin.
Is Glycerin safe during pregnancy?
Topical glycerin is generally considered safe during pregnancy. The CIR 2014 report reviewed reproductive toxicity studies in animals (rats, mice, and rabbits). The NOAEL for maternal toxicity and teratogenicity was 1,310 mg/kg/d in rats, 1,280 mg/kg/d in mice, and 1,180 mg/kg/d in rabbits — with no fetal abnormalities observed. No adverse effects were seen when rats consumed 20% glycerin in water throughout gestation and nursing. Note: these findings are from animal studies; no large-scale human clinical trials on topical glycerin during pregnancy have been published. Always consult your healthcare provider for personal advice.
Glycerin serum or cream — which is better?
Glycerin serums deliver concentrated hydration and absorb quickly, making them suitable for layering under other products. Glycerin creams combine hydration with occlusion, which may be more appropriate for dry skin or cold, low-humidity climates. For best results, apply a glycerin-rich serum on damp skin, then seal with a cream or moisturizer.
What is the ideal concentration of Glycerin?
Most consumer glycerin skincare products contain 2%–10%. Per CIR 2014 industry data, the maximum observed concentrations are 79.2% in leave-on products and 99.4% in rinse-off products — these are reported industry values, not recommended or regulatory limits. Concentrations above 20%–30% can feel sticky. In humid environments, even low concentrations can be effective at attracting moisture to the skin.

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